Polysaccharides

Polysaccharides are long chains of monosaccharide (simple sugar) units linked together by glycosidic bonds. They are complex carbohydrates that serve structural, storage, and functional roles in both plants and animals.


Structure:

  • Made up of repeating monosaccharides (e.g., glucose, galactose, mannose).
  • Can be:
    • Linear (e.g., cellulose)
    • Branched (e.g., glycogen, amylopectin)
  • Classified as:
    • Homopolysaccharides: All repeating units are the same sugar (e.g., starch made of glucose)
    • Heteropolysaccharides: Composed of different sugars (e.g., hyaluronic acid)

Functions:

FunctionDescriptionExamples
Energy storageReserve fuel for later useStarch (plants), Glycogen (animals)
Structural supportMaintain cell shape and structureCellulose (plants), Chitin (fungi, arthropods)
Biological signaling and protectionLubrication, immune modulationMucopolysaccharides (e.g., hyaluronic acid, heparin)

Examples of Polysaccharides:

PolysaccharideTypeRoleFound In
StarchHomopolysaccharide (glucose)Energy storage in plantsPotatoes, grains
GlycogenHomopolysaccharide (glucose)Energy storage in animalsLiver, muscles
CelluloseHomopolysaccharide (glucose)Structural support in plant cell wallsPlants
ChitinHomopolysaccharide (N-acetylglucosamine)Exoskeleton structureInsects, fungi
Hyaluronic acidHeteropolysaccharideLubrication, tissue hydrationConnective tissues, joints

Properties:

  • Insoluble or poorly soluble in water (especially structural polysaccharides like cellulose).
  • Can be digestible (starch, glycogen) or indigestible to humans (cellulose).
  • Vary greatly in size, branching, and chemical modifications, contributing to a wide range of functions.

Polysaccharides vs. Other Carbohydrates:

TypeStructureExampleDigestibility
MonosaccharideSingle sugar unitGlucoseEasily absorbed
DisaccharideTwo sugar unitsSucroseDigestible
PolysaccharideMany sugar unitsStarch, CelluloseVaries by type

Biological and Industrial Significance:

  • Nutrition: Major component of diet (e.g., dietary fiber from cellulose).
  • Pharmaceuticals: Used in drug delivery systems (e.g., dextran).
  • Biotechnology: Used as gelling agents (e.g., agar, alginate).
  • Medical applications: Hyaluronic acid in eye surgery and joint treatments.

Summary Table:

FeatureDescription
Basic UnitMonosaccharides (e.g., glucose)
Bond TypeGlycosidic bonds
FunctionStorage, structure, signaling
TypesHomo- and heteropolysaccharides
Common ExamplesStarch, glycogen, cellulose, chitin, hyaluronic acid